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PGM catalysts

PGM compounds

Rhodium compounds

Chlorotris (triphenylphosphine) rhodium (I)

Chlorotris (triphenylphosphine) rhodium(I)
 WILKINSON'S CATALYST
Compound
RhCl(P(C6H5)3)3



 

Color Crystal Form
maroon crystals
Molecular Weight
925.23
Metal Content
11.1%
C.A.S. No.
14694-95-2
Stability
deliquescence in air
Solubility
Soluble in most solvents(e.g. benzene, ethanol, chloroform, dichloromethane)  but with phosphine dissociation. Reacts with O2 in solution
Application Oxidation, somerization, hydroformylation, hydrogenation, hydrosilation
Storage
inert gas
Comments
reacts with oxygen in solution

Application

  • Catalyst for hydroboration of olefins
  • .A homogeneous hydrogenation catalyst which operates under mind condition.
  • Catalyst for the decarbonylation of aldehydes.
  • Catalyst for regio- and stereoselective allylic substitution reaction



 

 

 
 

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