Chlorotris(triphenylphosphine)rhodium(I), Rhodium Compounds

Chlorotris (triphenylphosphine) rhodium(I)
WILKINSON'S CATALYST

Compound	RhCl(P(C₆H₅)₃)₃
Color Crystal Form	maroon crystals
Molecular Weight	925.23
Metal Content	11.1%
C.A.S. No.	14694-95-2
Stability	deliquescence in air
Solubility	Soluble in most solvents(e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O₂ in solution
Application	Oxidation, somerization, hydroformylation, hydrogenation, hydrosilation
Storage	inert gas
Comments	reacts with oxygen in solution

Application
Catalyst for hydroboration of olefins .A homogeneous hydrogenation catalyst which operates under mind condition. Catalyst for the decarbonylation of aldehydes. Catalyst for regio- and stereoselective allylic substitution reaction

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